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Montmorillonite Kilinin HDPE/ HGS Kompozitlerinin Fiziksel Özellikleri Üzerindeki Etkisi

Year 2021, Volume: 21 Issue: 3, 735 - 744, 30.06.2021
https://doi.org/10.35414/akufemubid.889971

Abstract

Son zamanlarda, polimer nanokompozitlerin fiziksel özelliklerinin geliştirilmesine yönelik artan bir ilgi vardır. Bu çalışmada, montmorillonit (MMT) kil oranının (ağırlıkça% 0, 1, 5, 10 ve 15) yüksek yoğunluklu polietilen (HDPE) / içi boş cam küreler (HGS) kompozitlerinin fiziksel özellikleri üzerindeki etkisi araştırıldı. İçi boş cam küre oranı ağırlıkça % 20'dir. Ekstrüderden elde edilen karışım granüle edildikten sonra, bir enjeksiyon kalıplama makinesi kullanılarak test numuneleri üretildi. Erime akış indeksi belirleme testi (MFI), nem miktarı belirleme testi (MC), Vicat yumuşama noktası belirleme testi (VSP), yük altında eğilme sıcaklığı belirleme testi (HDT), sınırlayıcı oksijen indeksi belirleme testi (LOI) gibi fiziksel testler uygulandı. Nanokil dispersiyonu, X-ışını kırınımı (XRD) ile incelendi. HDPE / HGS / MMT-kil kompozitlerinin görüntüleri Taramalı elektron mikroskobu (SEM) ile alınmıştır. Elde edilen sonuçlar, MMT-kil içeriği arttıkça ısıl çarpılma sıcaklığının, Vicat yumuşama noktasının ve erime akış indeksinin kademeli olarak azaldığını göstermektedir. LOI, MMT-kil içeriğinin ağırlıkça yüzde 0'dan 15'e yükselmesiyle azaldı. MC, MMT-kil içeriğinin ağırlıkça yüzde 0'dan 1'e artmasıyla artmıştır. MC, MMT-kil içeriğinin ağırlıkça yüzde 10'a yükseltilmesiyle değişmedi. Daha sonra, MC, MMT-kil içeriğinin ağırlıkça % 10'dan% 15'e yükselmesiyle arttı.

References

  • Chawla K.K., 2012. Composite Materials. Springer Verlag New York, 80.
  • El-Sheikhy R and Al-Shamrani M., 2015. On the Processing and Properties of Clay/ Polymer Nanocomposites CPNC. Latin American Journal of Solids and Structures,12, 385-419.
  • Kaştan A., Yalçın Y., Ünal H. and Talaş Ş., 2017. Nanokil katkılı poliamid 6/yüksek yoğunluklu polietilen kompozitlerin termal özelliklerinin incelenmesi. Journal of the Faculty of Engineering and Architecture of Gazi University, 32:1, 97-107.
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  • Lei Y., Wu Q., Clemons M.C., Yao F and Xu Y., 2007. Influence of Nanoclay on Properties of HDPE/Wood Composites. Journal of Applied Polymer Science,106, 3958-3966.
  • Liang J.Z and Li F.H.., 2007. Heat transfer in polymer composites filled with inorganic hollow micro-spheres: A theoretical model. Polymer Testing, 26, 1025-1030.
  • Liu Sung-Po and Xu Jia-Fa, 2011. Characterization and mechanical properties of high density polyethylene/ silane montmorillonite nanocomposites. International Communications in Heat and Mass Transfer, 38, 734-741.
  • Mohan T.P and Kanny K., 2012. Effect of nanoclay in HDPE-glass fiber composites on processing, structure, and properties. Advanced Composite Materials, 21:4, 315-331.
  • Patankar S. N. and Kranov Y.A., 2009. Hollow glass microsphere HDPE composites for low energy sustainability. Materials Science and Engineering: A, 527, 1361-1366.
  • Sepet H., Tarakcıoglu N and Misra R., 2016. Investigation of mechanical, thermal and surface properties of nanoclay/HDPE nanocomposites produced industrially by melt mixing approach. Journal of Composite Materials, 50(22), 3105-3116.
  • Shah V., 1998. Handbook of Plastics Testing Technology. John Wiley & Sons, Inc., 174.
  • Singh V. P., Vimal K.K., Shashikant S., Kapur G.S. and Choudhary V., 2017. Polyethylene/sepiolite clay nanocomposites: Effect of clay content, compatibilizer polarity, and molar mass on viscoelastic and dynamic mechanical properties. Journal of Applied Polymer Science, 134, Issue 33, 1-13.
  • Taşdemir M. and Yerleşen U.,2015. Study on the friction and wear behaviors of modified HDPE/GLASS SPHERES Composites.Romanian Journal of Materials, 45(1), 59-66
  • Turaev E.R., Khashirova S.Yu and Bedanokov A. Yu, Dzhangurazov B. Zh., Mikitaev A.K., 2009. Nanocomposite materials based on high density polyethylene with increased thermomechanical and physicomechanical properties. Plasticheskie Massy, 9, 11-14.
  • Yung K. C., Zhu B.L. and Yue T.M., Xie C.S., 2009. Preparation and properties of hollow glasss microsphere-filled epoxy-matrix composites. Composites Science and Technology, 69, 260-264.

Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites

Year 2021, Volume: 21 Issue: 3, 735 - 744, 30.06.2021
https://doi.org/10.35414/akufemubid.889971

Abstract

Recently, there has been an increasing interest in enhancing the physical properties of polymer nanocomposites. In the present study, the effect of montmorillonite (MMT) clay ratio (0, 1, 5, 10 and 15 wt.%) on the physical properties of the high-density polyethylene (HDPE)/ hollow glass spheres (HGS) composites were investigated. The hollow glass spheres ratio is 20% by weight. After the mixture obtained from the extruder was granulated, test specimens were produced using an injection molding machine. Physical tests were applied such as melt flow index (MFI), moisture content (MC), Vicat softening point (VSP), heat deflection temperature (HDT), Limit oxygen index (LOI). The nanoclay dispersion was examined by X-ray diffraction (XRD). Images of HDPE/HGS/MMT-clay composites were taken with Scanning electron microscopy (SEM). The results obtained show that heat deflection temperature, Vicat softening point, and melt flow index decreased gradually as the MMT-clay content increased. The LOI decreased with increase in the MMT-clay content from 0 to 15wt. %. MC increased with increase in the MMT-clay content from 0 to 1 wt. %. MC didn’t change with further increasing of MMT-nanoclay content to 10 percent by weight. Then, MC increased with increase in the MMT-clay content from 10 to 15 wt. %.

References

  • Chawla K.K., 2012. Composite Materials. Springer Verlag New York, 80.
  • El-Sheikhy R and Al-Shamrani M., 2015. On the Processing and Properties of Clay/ Polymer Nanocomposites CPNC. Latin American Journal of Solids and Structures,12, 385-419.
  • Kaştan A., Yalçın Y., Ünal H. and Talaş Ş., 2017. Nanokil katkılı poliamid 6/yüksek yoğunluklu polietilen kompozitlerin termal özelliklerinin incelenmesi. Journal of the Faculty of Engineering and Architecture of Gazi University, 32:1, 97-107.
  • Kotal M and Bhowmick A.K., 2015. Polymer nanocomposites from modified clays: Recent advances and challenges. Progress in Polymer Science, 51, 127-187.
  • Lei Y., Wu Q., Clemons M.C., Yao F and Xu Y., 2007. Influence of Nanoclay on Properties of HDPE/Wood Composites. Journal of Applied Polymer Science,106, 3958-3966.
  • Liang J.Z and Li F.H.., 2007. Heat transfer in polymer composites filled with inorganic hollow micro-spheres: A theoretical model. Polymer Testing, 26, 1025-1030.
  • Liu Sung-Po and Xu Jia-Fa, 2011. Characterization and mechanical properties of high density polyethylene/ silane montmorillonite nanocomposites. International Communications in Heat and Mass Transfer, 38, 734-741.
  • Mohan T.P and Kanny K., 2012. Effect of nanoclay in HDPE-glass fiber composites on processing, structure, and properties. Advanced Composite Materials, 21:4, 315-331.
  • Patankar S. N. and Kranov Y.A., 2009. Hollow glass microsphere HDPE composites for low energy sustainability. Materials Science and Engineering: A, 527, 1361-1366.
  • Sepet H., Tarakcıoglu N and Misra R., 2016. Investigation of mechanical, thermal and surface properties of nanoclay/HDPE nanocomposites produced industrially by melt mixing approach. Journal of Composite Materials, 50(22), 3105-3116.
  • Shah V., 1998. Handbook of Plastics Testing Technology. John Wiley & Sons, Inc., 174.
  • Singh V. P., Vimal K.K., Shashikant S., Kapur G.S. and Choudhary V., 2017. Polyethylene/sepiolite clay nanocomposites: Effect of clay content, compatibilizer polarity, and molar mass on viscoelastic and dynamic mechanical properties. Journal of Applied Polymer Science, 134, Issue 33, 1-13.
  • Taşdemir M. and Yerleşen U.,2015. Study on the friction and wear behaviors of modified HDPE/GLASS SPHERES Composites.Romanian Journal of Materials, 45(1), 59-66
  • Turaev E.R., Khashirova S.Yu and Bedanokov A. Yu, Dzhangurazov B. Zh., Mikitaev A.K., 2009. Nanocomposite materials based on high density polyethylene with increased thermomechanical and physicomechanical properties. Plasticheskie Massy, 9, 11-14.
  • Yung K. C., Zhu B.L. and Yue T.M., Xie C.S., 2009. Preparation and properties of hollow glasss microsphere-filled epoxy-matrix composites. Composites Science and Technology, 69, 260-264.
There are 15 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Beril Gümüş 0000-0002-4185-4470

Publication Date June 30, 2021
Submission Date March 2, 2021
Published in Issue Year 2021 Volume: 21 Issue: 3

Cite

APA Gümüş, B. (2021). Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 21(3), 735-744. https://doi.org/10.35414/akufemubid.889971
AMA Gümüş B. Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. June 2021;21(3):735-744. doi:10.35414/akufemubid.889971
Chicago Gümüş, Beril. “Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 21, no. 3 (June 2021): 735-44. https://doi.org/10.35414/akufemubid.889971.
EndNote Gümüş B (June 1, 2021) Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 21 3 735–744.
IEEE B. Gümüş, “Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 21, no. 3, pp. 735–744, 2021, doi: 10.35414/akufemubid.889971.
ISNAD Gümüş, Beril. “Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 21/3 (June 2021), 735-744. https://doi.org/10.35414/akufemubid.889971.
JAMA Gümüş B. Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2021;21:735–744.
MLA Gümüş, Beril. “Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 21, no. 3, 2021, pp. 735-44, doi:10.35414/akufemubid.889971.
Vancouver Gümüş B. Effect of Montmorillonite Clay on Physical Properties of HDPE/ HGS Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2021;21(3):735-44.