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ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES

Year 2012, Volume: 13 Issue: 1, 31 - 49, 12.03.2012

Abstract

A modified suspension polymerization was used for the preparation of the mesoporous magnetic-poly(divinylbenzene-co-vinylimidazole) (m-poly(DVB-VIM)) microbeads in size 53-212 μm of average diameter. The specific surface area and the DVB/VIM mol ratio of the microspheres were determined as 29.47 m2/g and 1:4 mol/mol with Fe3O4, respectively. The physicochemical studies of adsorption of Ni(II) ions from aqueous solutions such as pH, initial concentration, amount of mesoporous m-poly(DVB-VIM) microbeads, contact time, and temperature onto the m-poly(DVBVIM) microspheres were carried out. The maximum adsorption capacities of the m-poly(DVB-VIM) microspheres towards Ni(II) ions were determined as 13.51, 20.14, 21.00 and 23.62 mg/g at 277 K, 298 K, 318 K, and 338 K, respectively. The dynamic and equilibrium adsorption behaviours of the system were adequately described by the pseudo-second-order kinetic and the Langmuir isotherm models, respectively. Various thermodynamic parameters, such as the Gibbs' free energy change ( Δ Go), the standard enthalpy change (Δ Ho) and the standard entropy change (Δ So) were also determined. Morever, after use in the adsorption, the m-poly(DVB-VIM) microbeads with paramagnetic property was separated from the via the applied magnetic force. These results indicate that the material studied could be used as a purifier for the removal of Ni(II) ions from water and wastewater under magnetic field.

 

 

References

  • Akgol, S., Kusvuran, E., Kara, A., Şenel, S. and Denizli, A. (2006). Porous dye affinity beads for nickel adsorption from aqueous solutions: A kinetic study. Journal Applied Polymer Science 100(6), 5056- 5065.
  • Bajpai, S.K. and Johnson, S. (2007). Removal of Ni2+ ions from aqueous solution by sorption into poly(acrylamide–co–sodium acrylate) hydrogels. Journal of Macromolecular Science A: Pure and Applied Chemistry 44(3), 285-290.
  • Bayramoglu, G., Senel, A.U. and Arica, M.Y. (2006). Effect of spacer-arm and Cu(II) ions on performance of l-histidine immo- bilized on poly(GMA/MMA) beads as an affinity ligand for separation and purifica- tion of IgG. Separation and Purifcation Technology 50(2), 229-239.
  • Chen, A.H., Liu, S.C. and Chen, C.Y. (2008). Comparative adsorption of Cu(II), Zn(II) and Pb(II) ions in aqueous solution on the crosslinked chitosan with epichlorohy- drin. Journal of Hazardous Materials 154(1-3), 184-191.
  • Daoud, F.B., Kaddour, S. and Sadoun, T. (2010). Adsorption of cellulase Aspergil- lus niger on a commercial activated car- bon: Kinetics and equilibrium studies. Colloids Surface B: 75(1), 93-99.
  • Dogan, M., Alkan, M. And Onganer, Y. (2000). Adsorption of methylene blue on perlite from aqueous solutions. Water Air Soil Pollution 120(3-4), 229-248.
  • Duan, G., Zhang, C., Li, A., Yang, X., Lu, L. and Wang, X. (2008). Preparation and characterization of mesoporous zirconia made by using a poly (methyl methacry- late) template. Nanoscale Research Letter 3(3), 118-122.
  • Freundlich, H.M.F. (1906). Über die adsorption in lösungen, Zeitschrift für Physikalische Chemie (Leipzig), 57A, 385-470.
  • Fu, L.J., Zhang, T., Cao, Q., Zhang, H.P. and Wu, Y.P. (2007). Preparation and charac- terization of three-dimensionally ordered mesoporous titania microparticles as ano- de material for lithium ion battery. Elect- rochemistry Communications 9(8), 2140- 2144.
  • Ghassabzadeh, H., Mohadespour, A., T- Mostaedi, M., Zaheri, P., Maragheh, M.G. and Taheri, H. (2010). Adsorption of Ag, Cu and Hg from aqueous solutions using expanded perlite. Journal of Hazardous Materials 177(1-3), 950-955.
  • Hanafiah, M.A.K.M., Zakaria, H. and Ngah, W.S.W. (2010). Base treated cogon grass (Imperata ylindrical) as an adsorbent for the removal of Ni(II): Kinetic, iso- thermal and fixed-bed column studies. Clean – Soil, Air, Water 38(3), 248-256.
  • Hanafiah, M.A.K.M., Zakaria, H. and Wan Ngah, W.S. (2009). Preparation, charac- terization, and adsorption behavior of Cu(II) ions onto alkali-treated weed (Im- perata cylindrica) leaf powder. Water Air Soil Pollution 201(1-4), 43-53.
  • Ho, Y.S. and McKay, G. (1999). Pseudo-second order model for sorption processes. Pro- cess Biochem. 34(5), 451-465.
  • Hua, M., Zhang, S., Pan, B., Zhang, W. and Zhang, L. Lv, Q. (2011). Heavy metal removal from water/wastewater by na- nosized metal oxides: A review. Journal of Hazardous Materials 211-212, 317- 331.
  • Kara, A. (2009). Adsorption of Cr(VI) ions onto poly(ethylene glycol dimethacrylate-1- vinil-1,2,4-triazol). Polymer Science 114(2), 948-955. Journal Applied
  • Kara, A., Uzun, L., Besirli, N. and Denizli, A. (2004). Poly(ethylene glycol dimethacry- late-n-vinyl imidazole) beads for heavy metal removal. Journal of Hazardous Ma- terials 106(2-3), 93-99.
  • Lagergren, S. (1898). Zur theorie der sogenan- nten adsorption gelöster stoffe. Kungliga Svenska Vetenskapsakademiens. Han- dlingar 24(4), 1-39.
  • Langmuir, I. (1916). The constitution and fun- damental properties of solids and liquids. Journal of the American Chemistry Society 38, 2221-2295.
  • Laus, R., Costa, T.G., Szpoganicz, B. and Fáve- re, V.T. (2010). Adsorption and desorp- tion of Cu(II), Cd(II) and Pb(II) ions using chitosan crosslinked with epichlo- rohydrin-triphosphate as the adsorbent. Journal of Hazardous Materials 183(1-3), 233-241.
  • Mahdavian, A.R. and Mirrahim, M.A.S. (2010). Efficient separation of heavy metal cati- ons by anchoring polyacrylic acid on su- perparamagnetic magnetite nanoparticles through surface modification. Chemical Engineering Journal 159(1-3), 264-271.
  • Monier, M., Ayad, D.M., Wei, Y. and Sarhan, A.A. (2010). Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chi- tosan chelating resin. Journal of Hazar- dous Materials 177(1-3), 962-970.
  • Namasivayam, C. and Kavita, D. (2002). Remo- val of congo red from water by adsorption on to activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigment 54(1), 47-58.
  • Ngah, W.S.W. and Fatinathan, S. (2010). Ad- sorption characterization of Pb(II) and Cu(II) ions onto chitosan- tripolyphosphate beads: Kinetic, equilib- rium and thermodynamic studies. Journal of Environmental Management 91(4), 958-969.
  • Olgun, A. and Atar, N. (2011). Removal of cop- per and cobalt from aqueous solution onto waste containing boron impurity. Chemi- cal Engineering Journal 167(1), 140-147.
  • Osman, B., Kara, A. and Besirli, N. (2011). Im- mobilization of glucoamylase onto Lewis metal ion chelated magnetic affinity sorbent: kinetic, isotherm and thermody- namic studies. Journal of Macromolecu- lar Science Pure & Applied Chemistry 48(5), 387-399.
  • Ozay, O., Ekici, S., Baran, Y., Aktas, N. and Sahiner, N. (2009). Removal of toxic metal ions with magnetic hydrogels. Water Research 43(17), 4403-4411.
  • Ozcan, A., Ozcan, A.S., Tunali, S., Akar, T. and Kiran, I. (2005). Determination of the equilibrium, kinetic and thermodynamic parameters of adsorption of copper(II) ions onto seeds of capsicum annuum. Journal of Hazardous Materials 124(1-3), 200-208.
  • Ozer, A., Ozer, D. and Ozer, A. (2004). The ad- sorption of copper(II) ions on to dehy- drated wheat bran (DWB): Determination of the equilibrium and thermodynamic pa- rameters. Process Biochemistry 39(12), 2183-2191.
  • Patil, A.K. and Shrivastava, V.S. (2010). Ad- sorption of Ni(II) from aqueous solution on Delonix regia (Gulmohar) tree bark. Ar. Applied Science Resource 2(2), 404- 413.
  • Plazinski, W., Rudzinski, W. and Plazinska, A. (2009). Theoretical models of sorption kinetics including a surface reaction mechanism: A review. Adv. Colloid Inter- face Science 152(1-2), 2-13.
  • Restani, R.B., Correia, V.G., Bonifácio, V.D.B. and A.-Ricardo, A. (2010). Development of functional mesoporous microparticles for controlled drug delivery. Journal of Supercri. Fluids 55(1), 333-339.
  • Ritchie, A.G. (1977). Alternative to the Elovich equation for the kinetics of adsorption of gases on solids. Journal of Chemistry Soc. Faraday Trans. 73, 1650-1653.
  • Senel, S., Uzun, L., Kara, A. and Denizli, A. (2008). Heavy metal removal from syn- thetic solutions with magnetic beads un- der magnetic field. Journal of Macromo- lecular Science Pure & Applied Chemis- try A 45(8), 635-642.
  • Souza, K.C., Ardisson, J.D. and Sousa, E.M.B. (2009). Study of mesoporous sili- ca/magnetite systems in drug controlled release. Journal of Materials Science: Materials in Medicine 20(2), 507-512.
  • Strkalj, A., Radenovic, A. and Malina, J. (2010). Nickel adsorption onto carbon anode dust modified by acetic acid and KOH. Jour- nal of Mining and Metallurg Section B- Metall. 46 (1), 33-40.
  • Taqvi, S.I.H., Hasany, S.M. and Bhanger, M.I. (2008). Sorptive potential of beach sand to remove Ni(II) ions: An Equilibrium isotherm study. Clean – Soil, Air, Water 36(4), 366-372.
  • Tassist, A., Lounici, H., Abdi, N. and Mameri, N. (2010). Equilibrium, kinetic and ther- modynamic studies on aluminum biosorp- tion by a mycelial biomass (Streptomyces rimosus). Journal of Hazardous Materials 183(1-3), 35-43.
  • Tripathy, S.S. and Raichur, A.M. (2008). Abatement of fluoride from water using manganese dioxide-coated activated alu- mina. Journal Hazardous Materials 153(3), 1043-1051.
  • Tseng, J.Y., Chang, C.Y., Chen, Y.H., Chang, C.F. and Chiang, P.C. (2007). Synthesis of micro-size magnetic polymer adsorbent and its application for the removal of Cu(II) ion. Colloids Surface A: 295(1-3), 209-216.
  • Unlu, N. and Ersoz, M. (2006). Adsorption characteristics of heavy metal ions onto a low cost biopolymeric sorbent from aque- ous solutions. Journal Hazardous Materi- als B 136(2), 272-280.
  • Wang, X.S., Ren, J.J., Lu, H.J., Zhu, L., Liu, F., Zhang, Q. and Xie, J. (2010). Removal of Ni(II) from aqueous solutions by nanosca- le magnetite. Clean–Soil Air Water 38(12), 1131-1136.
  • Zhao, Z., Wang, X., Zhao, C., Zhu, X. and Du, S. (2010). Adsorption and desorption of antimony acetate on sodium montmoril- lonite. Journal of Colloid Interface Science 345(2), 154-159.
  • Zhou, Y.T., White, C.B., Nie, H.L. and Zhu, L.M. (2009). Adsorption mechanism of Cu2+ from aqueous solution by chitosan- coated magnetic nanoparticles modified with α-ketoglutaric acid. Colloids Surface B: Biointerfaces 74(1), 244-252.

MANYETİK-POLİ (DİVİNİLBENZEN-KO-VİNİLİMİDAZOL) MİKROKÜRELER İLE SULU ÇÖZELTİLERDEN Ni(II) İYONLARININ ADSORPSİYONU: FİZİKOKİMYASAL ÇALIŞMALARI

Year 2012, Volume: 13 Issue: 1, 31 - 49, 12.03.2012

Abstract

Ortalama çapı 53-212 μm olan mezogözenekli manyetik-poli(divinilbenzen-ko-vinilimidazol) (mpoli(DVB-VIM)) mikrokürelerinin hazırlanması için modifiye süspansiyon polimerizasyonu kullanıldı. Mikrokürelerin spesifik yüzey alanı 29.47 m2g-1 ve Fe3O4 ilavesiyle birlikte, DVB/VIM mol oranı 4:1 mol/mol olarak belirlendi. Fizikokimyasal çalışmalar m-poli (DVB-VIM) mikroküreleri üzerine pH, başlangıç konsantrasyonu, mikroküre miktarı, temas süresi ve sıcaklık gibi parametrelerle incelendi. m-poli(DVB-VIM) mikrokürelerinin Ni(II) iyonlarına karşı maksimum adsorpsiyon kapasitesi 277 K, 298 K, 318 K ve 338 K’de sırasıyla 13.51, 20.14, 21.00 ve 23.62 mg.g-1 olarak belirlendi. Sistemin dinamik ve denge adsorpsiyon davranışları sırasıyla yalancı ikinci derece model ve Langmuir izoterm modeliyle açıklandı. Gibbs serbest enerji değişimi (ΔG0), standart entalpi değişimi (ΔH0) ve standart entropi değişimi (ΔS0) gibi termodinamik parametreler belirlendi. Ayrıca adsorpsiyonda kullanımdan sonra, paramanyetik özellikli m-poli (DVB-VIM) mikroküreleri uygulanan manyetik kuvvet yardımıyla ayrıldı. Bu sonuçlar, çalışılan malzemenin manyetik alan altında su ve atık sulardan Ni(II) iyonlarının uzaklaştırılması için kullanılabilir olduğunu gösterdi.

References

  • Akgol, S., Kusvuran, E., Kara, A., Şenel, S. and Denizli, A. (2006). Porous dye affinity beads for nickel adsorption from aqueous solutions: A kinetic study. Journal Applied Polymer Science 100(6), 5056- 5065.
  • Bajpai, S.K. and Johnson, S. (2007). Removal of Ni2+ ions from aqueous solution by sorption into poly(acrylamide–co–sodium acrylate) hydrogels. Journal of Macromolecular Science A: Pure and Applied Chemistry 44(3), 285-290.
  • Bayramoglu, G., Senel, A.U. and Arica, M.Y. (2006). Effect of spacer-arm and Cu(II) ions on performance of l-histidine immo- bilized on poly(GMA/MMA) beads as an affinity ligand for separation and purifica- tion of IgG. Separation and Purifcation Technology 50(2), 229-239.
  • Chen, A.H., Liu, S.C. and Chen, C.Y. (2008). Comparative adsorption of Cu(II), Zn(II) and Pb(II) ions in aqueous solution on the crosslinked chitosan with epichlorohy- drin. Journal of Hazardous Materials 154(1-3), 184-191.
  • Daoud, F.B., Kaddour, S. and Sadoun, T. (2010). Adsorption of cellulase Aspergil- lus niger on a commercial activated car- bon: Kinetics and equilibrium studies. Colloids Surface B: 75(1), 93-99.
  • Dogan, M., Alkan, M. And Onganer, Y. (2000). Adsorption of methylene blue on perlite from aqueous solutions. Water Air Soil Pollution 120(3-4), 229-248.
  • Duan, G., Zhang, C., Li, A., Yang, X., Lu, L. and Wang, X. (2008). Preparation and characterization of mesoporous zirconia made by using a poly (methyl methacry- late) template. Nanoscale Research Letter 3(3), 118-122.
  • Freundlich, H.M.F. (1906). Über die adsorption in lösungen, Zeitschrift für Physikalische Chemie (Leipzig), 57A, 385-470.
  • Fu, L.J., Zhang, T., Cao, Q., Zhang, H.P. and Wu, Y.P. (2007). Preparation and charac- terization of three-dimensionally ordered mesoporous titania microparticles as ano- de material for lithium ion battery. Elect- rochemistry Communications 9(8), 2140- 2144.
  • Ghassabzadeh, H., Mohadespour, A., T- Mostaedi, M., Zaheri, P., Maragheh, M.G. and Taheri, H. (2010). Adsorption of Ag, Cu and Hg from aqueous solutions using expanded perlite. Journal of Hazardous Materials 177(1-3), 950-955.
  • Hanafiah, M.A.K.M., Zakaria, H. and Ngah, W.S.W. (2010). Base treated cogon grass (Imperata ylindrical) as an adsorbent for the removal of Ni(II): Kinetic, iso- thermal and fixed-bed column studies. Clean – Soil, Air, Water 38(3), 248-256.
  • Hanafiah, M.A.K.M., Zakaria, H. and Wan Ngah, W.S. (2009). Preparation, charac- terization, and adsorption behavior of Cu(II) ions onto alkali-treated weed (Im- perata cylindrica) leaf powder. Water Air Soil Pollution 201(1-4), 43-53.
  • Ho, Y.S. and McKay, G. (1999). Pseudo-second order model for sorption processes. Pro- cess Biochem. 34(5), 451-465.
  • Hua, M., Zhang, S., Pan, B., Zhang, W. and Zhang, L. Lv, Q. (2011). Heavy metal removal from water/wastewater by na- nosized metal oxides: A review. Journal of Hazardous Materials 211-212, 317- 331.
  • Kara, A. (2009). Adsorption of Cr(VI) ions onto poly(ethylene glycol dimethacrylate-1- vinil-1,2,4-triazol). Polymer Science 114(2), 948-955. Journal Applied
  • Kara, A., Uzun, L., Besirli, N. and Denizli, A. (2004). Poly(ethylene glycol dimethacry- late-n-vinyl imidazole) beads for heavy metal removal. Journal of Hazardous Ma- terials 106(2-3), 93-99.
  • Lagergren, S. (1898). Zur theorie der sogenan- nten adsorption gelöster stoffe. Kungliga Svenska Vetenskapsakademiens. Han- dlingar 24(4), 1-39.
  • Langmuir, I. (1916). The constitution and fun- damental properties of solids and liquids. Journal of the American Chemistry Society 38, 2221-2295.
  • Laus, R., Costa, T.G., Szpoganicz, B. and Fáve- re, V.T. (2010). Adsorption and desorp- tion of Cu(II), Cd(II) and Pb(II) ions using chitosan crosslinked with epichlo- rohydrin-triphosphate as the adsorbent. Journal of Hazardous Materials 183(1-3), 233-241.
  • Mahdavian, A.R. and Mirrahim, M.A.S. (2010). Efficient separation of heavy metal cati- ons by anchoring polyacrylic acid on su- perparamagnetic magnetite nanoparticles through surface modification. Chemical Engineering Journal 159(1-3), 264-271.
  • Monier, M., Ayad, D.M., Wei, Y. and Sarhan, A.A. (2010). Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chi- tosan chelating resin. Journal of Hazar- dous Materials 177(1-3), 962-970.
  • Namasivayam, C. and Kavita, D. (2002). Remo- val of congo red from water by adsorption on to activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigment 54(1), 47-58.
  • Ngah, W.S.W. and Fatinathan, S. (2010). Ad- sorption characterization of Pb(II) and Cu(II) ions onto chitosan- tripolyphosphate beads: Kinetic, equilib- rium and thermodynamic studies. Journal of Environmental Management 91(4), 958-969.
  • Olgun, A. and Atar, N. (2011). Removal of cop- per and cobalt from aqueous solution onto waste containing boron impurity. Chemi- cal Engineering Journal 167(1), 140-147.
  • Osman, B., Kara, A. and Besirli, N. (2011). Im- mobilization of glucoamylase onto Lewis metal ion chelated magnetic affinity sorbent: kinetic, isotherm and thermody- namic studies. Journal of Macromolecu- lar Science Pure & Applied Chemistry 48(5), 387-399.
  • Ozay, O., Ekici, S., Baran, Y., Aktas, N. and Sahiner, N. (2009). Removal of toxic metal ions with magnetic hydrogels. Water Research 43(17), 4403-4411.
  • Ozcan, A., Ozcan, A.S., Tunali, S., Akar, T. and Kiran, I. (2005). Determination of the equilibrium, kinetic and thermodynamic parameters of adsorption of copper(II) ions onto seeds of capsicum annuum. Journal of Hazardous Materials 124(1-3), 200-208.
  • Ozer, A., Ozer, D. and Ozer, A. (2004). The ad- sorption of copper(II) ions on to dehy- drated wheat bran (DWB): Determination of the equilibrium and thermodynamic pa- rameters. Process Biochemistry 39(12), 2183-2191.
  • Patil, A.K. and Shrivastava, V.S. (2010). Ad- sorption of Ni(II) from aqueous solution on Delonix regia (Gulmohar) tree bark. Ar. Applied Science Resource 2(2), 404- 413.
  • Plazinski, W., Rudzinski, W. and Plazinska, A. (2009). Theoretical models of sorption kinetics including a surface reaction mechanism: A review. Adv. Colloid Inter- face Science 152(1-2), 2-13.
  • Restani, R.B., Correia, V.G., Bonifácio, V.D.B. and A.-Ricardo, A. (2010). Development of functional mesoporous microparticles for controlled drug delivery. Journal of Supercri. Fluids 55(1), 333-339.
  • Ritchie, A.G. (1977). Alternative to the Elovich equation for the kinetics of adsorption of gases on solids. Journal of Chemistry Soc. Faraday Trans. 73, 1650-1653.
  • Senel, S., Uzun, L., Kara, A. and Denizli, A. (2008). Heavy metal removal from syn- thetic solutions with magnetic beads un- der magnetic field. Journal of Macromo- lecular Science Pure & Applied Chemis- try A 45(8), 635-642.
  • Souza, K.C., Ardisson, J.D. and Sousa, E.M.B. (2009). Study of mesoporous sili- ca/magnetite systems in drug controlled release. Journal of Materials Science: Materials in Medicine 20(2), 507-512.
  • Strkalj, A., Radenovic, A. and Malina, J. (2010). Nickel adsorption onto carbon anode dust modified by acetic acid and KOH. Jour- nal of Mining and Metallurg Section B- Metall. 46 (1), 33-40.
  • Taqvi, S.I.H., Hasany, S.M. and Bhanger, M.I. (2008). Sorptive potential of beach sand to remove Ni(II) ions: An Equilibrium isotherm study. Clean – Soil, Air, Water 36(4), 366-372.
  • Tassist, A., Lounici, H., Abdi, N. and Mameri, N. (2010). Equilibrium, kinetic and ther- modynamic studies on aluminum biosorp- tion by a mycelial biomass (Streptomyces rimosus). Journal of Hazardous Materials 183(1-3), 35-43.
  • Tripathy, S.S. and Raichur, A.M. (2008). Abatement of fluoride from water using manganese dioxide-coated activated alu- mina. Journal Hazardous Materials 153(3), 1043-1051.
  • Tseng, J.Y., Chang, C.Y., Chen, Y.H., Chang, C.F. and Chiang, P.C. (2007). Synthesis of micro-size magnetic polymer adsorbent and its application for the removal of Cu(II) ion. Colloids Surface A: 295(1-3), 209-216.
  • Unlu, N. and Ersoz, M. (2006). Adsorption characteristics of heavy metal ions onto a low cost biopolymeric sorbent from aque- ous solutions. Journal Hazardous Materi- als B 136(2), 272-280.
  • Wang, X.S., Ren, J.J., Lu, H.J., Zhu, L., Liu, F., Zhang, Q. and Xie, J. (2010). Removal of Ni(II) from aqueous solutions by nanosca- le magnetite. Clean–Soil Air Water 38(12), 1131-1136.
  • Zhao, Z., Wang, X., Zhao, C., Zhu, X. and Du, S. (2010). Adsorption and desorption of antimony acetate on sodium montmoril- lonite. Journal of Colloid Interface Science 345(2), 154-159.
  • Zhou, Y.T., White, C.B., Nie, H.L. and Zhu, L.M. (2009). Adsorption mechanism of Cu2+ from aqueous solution by chitosan- coated magnetic nanoparticles modified with α-ketoglutaric acid. Colloids Surface B: Biointerfaces 74(1), 244-252.
There are 43 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Ali Kara

Emel Demirbel This is me

Publication Date March 12, 2012
Published in Issue Year 2012 Volume: 13 Issue: 1

Cite

APA Kara, A., & Demirbel, E. (2012). ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 13(1), 31-49.
AMA Kara A, Demirbel E. ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES. AUJST-A. August 2012;13(1):31-49.
Chicago Kara, Ali, and Emel Demirbel. “ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 13, no. 1 (August 2012): 31-49.
EndNote Kara A, Demirbel E (August 1, 2012) ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 13 1 31–49.
IEEE A. Kara and E. Demirbel, “ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES”, AUJST-A, vol. 13, no. 1, pp. 31–49, 2012.
ISNAD Kara, Ali - Demirbel, Emel. “ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 13/1 (August 2012), 31-49.
JAMA Kara A, Demirbel E. ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES. AUJST-A. 2012;13:31–49.
MLA Kara, Ali and Emel Demirbel. “ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 13, no. 1, 2012, pp. 31-49.
Vancouver Kara A, Demirbel E. ADSORPTION OF Ni(II) IONS FROM AQUEOUS SOLUTIONS ONTO MAGNETIC POLY( DIVINYLBENZENE-CO-VINYLIMIDAZOLE) MICROBEADS: PHYSICOCHEMICAL STUDIES. AUJST-A. 2012;13(1):31-49.